Diversified applications of chemically modified 1,2-polybutadiene.

Biodegradation of Styrene-Butadiene-Styrene Coploymer via Sugars Attached to the Polymer Chain

A synthetic method was developed to chemically attach few molecules of simple sugars like glucose, mannose, galactose, maltose and xylose (0.09 0.37 wt%) and with quaternary nitrogen pendants (0.42 0.46 atomic%) along the polybutadiene section of polystyrene-block-polybutadiene-block-polystyrene (SBS) block copolymer. These functionalized SBS copolymers were evaluated for biodegradation using t...

Mechanical and Thermal Properties of Chemically Modified Epoxy Resin

Diglycidyl ether of bisphenol-A (DGEBA), having number average molecular weight (Mn) 375, was modified by incorporating the hydroxyl terminated polybutadiene (HTPB) based prepolymer using isophorone diisocyanate as a coupling agent. To increase the compatibility between the epoxy resin and HTPB part, polar groups were introduced in the later to achieve physical and chemical interactions between...

Nanoscale Patterning of Barium Titanate on Block Copolymers

Atriblock copolymerof polystyrene-polybutadiene-polystyrene (KratonD1102)hasbeenused topattern barium titanate precursor with nanoscale modulations. The copolymer self-assembles to yield cylindrical polystyrene nanodomains in a polybutadiene matrix. The preorganized thin films of polymer are then selectively OH-functionalized in situ on the unsaturated carbon bonds in the polybutadiene matrix w...

Biosorption of cobalt (II) by Inta ct and Chemically Modified Brown Algae: Optimization Using Resp onse Surface Methodology and Equilibrium, Dynamics and Thermodynamics Studies

1,2-Polybutadiene Latices by Catalytic Polymerization in Aqueous Emulsion

Catalytic aqueous polymerization of butadiene by the cobalt catalyst system [Co(C8H13)(C4H6)]/CS2 affords colloidally stable latices of highly crystalline syndiotactic 1,2-polybutadiene (Tm ) 190 °C, ∆Hc ) 60 J/g, Mw ∼ 105 g/mol, 97% 1,2, 3% 1,4-cis). Catalyst modification with reagents containing electrophilic carbon atoms (e.g., aromatic formamides) strongly decreases polymer crystallinity (T...